Firestone Natural Rubber Company
Material Safety Data Sheet
July 8, 2005 Page: 1
SECTION 1: PRODUCT IDENTIFICATION
Product Name: Hartex 101 Natural Rubber Latex
Chemical Name / Synonym: Natural Rubber
Chemical Family: Natural Rubber
24-Hour Emergency Phone: Transportation Emergency: (Chemtrec) (800) 424-9300
International Chemtrec: 703-527-3887 (call collect)
Manufacturer's Name: Firestone Natural Rubber Company
A Division of BFS Diversified Products, LLC
Manufacturer's Address: 310 East 96th Street
Indianapolis, IN 46240
NFPA Hazard Rating: Health 1, Flammability 0, Reactivity 0
HMIS Hazard Rating: Health 1, Flammability 0, Reactivity 0
OSHA Hazardous: No
SECTION 2: CHEMICAL COMPOSITION
Chemical Name:
Common
Name: CAS #: % (by wt) Exposure Limits:
Ammonia Ammonia 7664-41-7 <0.3 PEL 50 ppm
TLV 25 ppm
ACGIH STEL 35 ppm
Nonhazardous as per 29
CFR 1910.1200.
None None >99 None Established
Note: Zinc oxide and tetramethylthiuram disulfide have been added at trace amounts (<0.04% and
<0.04% respectively) as preservatives. Due to miniscule concentrations, are not anticipated to be a
chemical hazard, but are listed for general purpose information only.
SECTION 3: HAZARD IDENTIFICATION
Primary Route of Exposure: Eye contact, inhalation.
Signs and Symptoms of
Exposure:
Due to ammonia presence, contact with eye may result in
irritation, redness, tearing and blurred vision; and respiratory
tract may become irritated. Prolonged skin contact with latex
may result in irritation.
Medical Conditions Aggravated
by Exposure:
Impaired pulmonary function.
Chronic Effects: While none are known directly associated with this product,
note that NIOSH published an alert (no. 97-1375, June 1997)
that reported workers exposed to latex gloves and other
products containing natural rubber latex may develop allergic
reactions such as skin rashes; hives; nasal, eye, or sinus
symptoms; asthma; and (rarely) shock.
Carcinogenicity: None
SECTION 4: FIRST AID MEASURES
First Aid Procedures: Eye contact – wash eyes immediately with large amounts of
water. Get medical attention. Skin contact – flush skin with
large amounts of water. If irritation is present after washing,
Firestone Natural Rubber Company
Material Safety Data Sheet
July 8, 2005 Page: 2
get medical attention. Inhalation – move victim to fresh air.
Ingestion – seek immediate medical attention. The latex will
coagulate (solidify) in the digestive tract.
SECTION 5: FIRE FIGHTING PROCEDURES
Suitable Extinguishing Media: Foam, water, dry chemical, or carbon dioxide
Hazardous Combustion Products: Carbon dioxide and carbon monoxide.
Recommended Fire Fighting
Procedures:
Use SCBA and ordinary fire-fighting equipment.
Unusual Fire and Explosion
Hazards:
None Known.
SECTION 6: PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken in Case
Material is Released or Spilled:
Flush minor spills or leaks with water. Large spills can be
coagulated with 0.3% calcium chloride.
Precautions to Be Taken in
Handling and Storing:
Avoid inhalation of ammonia vapors. Keep container closed
when not in use.
SECTION 7: EXPOSURE CONTROLS / PERSONAL PROTECTION
Ventilation: No special ventilation requirements unless ammonia
concentration must be controlled.
Respiratory Protection: Use effective respiratory protection to protect against
ammonia vapors if exposure limit is exceeded.
Eye Protection: Goggles or face shield if splashing is a possibility.
Skin Protection: Neoprene or nitrile to avoid contact with latex.
Other: None required.
Work / Hygienic Practices: Wash exposed skin prior to eating, drinking or smoking and at
the end of each shift. Wash contaminated clothing prior to
reuse.
SECTION 8: PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: White, milky liquid with ammonia odor.
Flash Point: Not Applicable Lower Explosive Limit: None
Method Used: Not Applicable. Upper Explosive Limit: None
Evaporation Rate: 1 (water = 1) Boiling Point: 100?C1
pH (undiluted product): Not Applicable Melting Point: Not
Applicable
Solubility in Water: Dispersible Specific Gravity: >0.93
Vapor Density: 0.631 Percent Volatile: Unknown
Vapor Pressure: 760 mm Hg1
1 For the water phase only.
SECTION 9: STABILITY AND REACTIVITY
Thermal Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Contact with acids or salts will cause coagulation. This is not
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Material Safety Data Sheet
July 8, 2005 Page: 3
hazardous.
SECTION 10: TRANSPORTATION
Regulatory Agency: Not regulated
Proper Shipping Name: Not Applicable
Hazard Classification: Not Applicable
Identification Number: Not Applicable
Labels Required: Not Applicable
Other Requirements: Not Applicable
SECTION 11: MISCELLANEOUS INFORMATION
Additional Comments: The health hazards associated with this product are due
primarily to the presence of ammonia. Ammonia may be
released during handling of the latex in an open container.
Ammonia has an extremely low threshold odor (<1 ppm).
Therefore, the odor of ammonia will be noticeable and may
produce discomfort, even though the airborne concentrations
may be below the OSHA PEL or the ACGIH TLV. The user
must determine the employee exposure to ammonia in his/her
facility.
Date of Previous MSDS: June 14, 2005
Changes Since Previous MSDS: Formatting.
Telephone Number for Additional
Information:
(330) 379-7741
DISCLAIMER
The information contained herein is based on data considered accurate which has been obtained from
other companies and organizations. However, no warranty or representation is expressed or implied that
the information, is accurate, complete or representative. Firestone Natural Rubber Company, a subsidiary
of Bridgestone/Firestone Diversified Products, LLC, assumes no responsibility for injury to the buyer, the
buyer's employees, or any third persons, if reasonable safety procedures are not followed. Additionally,
Firestone Natural Rubber Company assumes no responsibility for injury to buyer, the buyer's employees,
or any third persons caused by abnormal use of this material, even if reasonable safety procedures are
followed.